Start here. This is the direct spoken answer to practice first.
Overview
Pairwise and absolute grading answer different evaluation questions.
Pairwise comparison asks which of two outputs better satisfies a scoring guide, so it is useful when comparing a prompt, model, or system change. Absolute scoring asks whether one output meets a defined standard, so it is better for obligations such as no unsupported claims or valid escalation behavior. I often use pairwise results to choose a candidate and absolute gates to decide whether it is safe to release.